{"created":"2024-02-01T05:19:13.337184+00:00","id":2000068,"links":{},"metadata":{"_buckets":{"deposit":"c6dba952-ca1a-44a7-b5b6-7ec2d1e30149"},"_deposit":{"created_by":8,"id":"2000068","owner":"8","owners":[8],"pid":{"revision_id":0,"type":"depid","value":"2000068"},"status":"published"},"_oai":{"id":"oai:nara-edu.repo.nii.ac.jp:02000068","sets":["1292:1298:1704865662204"]},"author_link":[],"control_number":"2000068","item_3_biblio_info_6":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2023-11-30","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"2","bibliographicPageEnd":"10","bibliographicPageStart":"1","bibliographicVolumeNumber":"72","bibliographic_titles":[{"bibliographic_title":"奈良教育大学紀要. 自然科学","bibliographic_titleLang":"ja"},{"bibliographic_title":"Bulletin of Nara University of Education. Natural Science","bibliographic_titleLang":"en"}]}]},"item_3_description_4":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"Electron Spin Resonance (ESR) spectroscopic studies directed at clarifying the fundamentals of radical polymerizations have been conducted. Optimization of measurement conditions allows direct detection of radicals in polymerization reactions and well-resolved ESR spectra can be obtained. The spectra provide information not only on the structure, properties, and concentration of radicals but also information on the initiating and propagating (oligomeric and polymeric) radicals in radical \npolymerizations. The key to the detection of well-resolved spectra in higher sensitivity, repeated optimization of the measurement conditions was essential. In this manuscript, we summarize a history of our efforts to obtain clear and well-resolved ESR spectra with commercially available spectrometer under repeated optimizations of various aspects of measurements. Interpretations of ESR spectra can clarify electronic structures of the radicals through analyses of hyperfine splitting constants.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_3_full_name_2":{"attribute_name":"著者(ヨミ)","attribute_value_mlt":[{"names":[{"name":"イチムラ,マユ","nameLang":"ja"},{"name":"タツミ,テツヤ","nameLang":"ja"},{"name":"ナカジマ,ヒロキ","nameLang":"ja"},{"name":"カジワラ,アツシ","nameLang":"ja"}]}]},"item_3_full_name_3":{"attribute_name":"著者別名","attribute_value_mlt":[{"names":[{"name":"ICHIMURA ,Mayu","nameLang":"en"},{"name":"TATSUMI, Tetsuya","nameLang":"en"},{"name":"NAKAJIMA ,Hiroki","nameLang":"en"},{"name":"KAJIWARA ,Atsush","nameLang":"en"}]}]},"item_3_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.20636/0002000068","subitem_identifier_reg_type":"JaLC"}]},"item_3_publisher_32":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"奈良教育大学","subitem_publisher_language":"ja"}]},"item_3_source_id_7":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"05472407","subitem_source_identifier_type":"PISSN"}]},"item_3_source_id_9":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AN00181070","subitem_source_identifier_type":"NCID"}]},"item_3_version_type_15":{"attribute_name":"著者版フラグ","attribute_value_mlt":[{"subitem_version_type":"VoR"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"市村,真優","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"辰巳,哲也","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"仲島,浩紀","creatorNameLang":"ja"}]},{"creatorNames":[{"creatorName":"梶原,篤","creatorNameLang":"ja"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2024-02-05"}],"filename":"NUE72_2_1-9.pdf","filesize":[{"value":"2.5 MB"}],"format":"application/pdf","mimetype":"application/pdf","url":{"url":"https://nara-edu.repo.nii.ac.jp/record/2000068/files/NUE72_2_1-9.pdf"},"version_id":"0ae6b85b-e51b-40f2-834a-db0dde12b116"}]},"item_keyword":{"attribute_name":"キーワード","attribute_value_mlt":[{"subitem_subject":"ラジカル重合","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"成長ラジカル","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"電子スピン共鳴","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"ESR","subitem_subject_language":"ja","subitem_subject_scheme":"Other"},{"subitem_subject":"Radical Polymerization","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Propagating Radical","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"Electron Spin Resonance","subitem_subject_language":"en","subitem_subject_scheme":"Other"},{"subitem_subject":"ESR","subitem_subject_language":"en","subitem_subject_scheme":"Other"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"jpn"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper"}]},"item_title":"ラジカル重合研究のための電子スピン共鳴分光（ESR）スペクトル測定法─事例1：定常状態ESR（SS ESR）の場合─","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"ラジカル重合研究のための電子スピン共鳴分光（ESR）スペクトル測定法─事例1：定常状態ESR（SS ESR）の場合─","subitem_title_language":"ja"},{"subitem_title":"Technical Aspects of Measurements of Propagating Radicals in Radical Polymerizations using Electron Spin Resonance （ESR） spectroscopy −Case 1: For the case of Steady-state ESR （SS ESR）−","subitem_title_language":"en"}]},"item_type_id":"3","owner":"8","path":["1704865662204"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-02-05"},"publish_date":"2024-02-05","publish_status":"0","recid":"2000068","relation_version_is_last":true,"title":["ラジカル重合研究のための電子スピン共鳴分光（ESR）スペクトル測定法─事例1：定常状態ESR（SS ESR）の場合─"],"weko_creator_id":"8","weko_shared_id":-1},"updated":"2024-02-26T06:29:03.770476+00:00"}