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非水溶媒中の銅(II)錯体の電極反応 －Py, SCN￣ および I￣ を配位子とする Cu(II) 錯体の非水溶媒ポーラログラフィー－
http://hdl.handle.net/10105/2522
http://hdl.handle.net/10105/2522e45d1ed3-2936-4c80-9ec3-9e53c1c4c82c
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
NUE26_2_7-13.pdf (311.9 kB)
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| アイテムタイプ | 紀要論文 / Departmental Bulletin Paper(1) | |||||||
|---|---|---|---|---|---|---|---|---|
| 公開日 | 2010-02-24 | |||||||
| タイトル | ||||||||
| タイトル | 非水溶媒中の銅(II)錯体の電極反応 －Py, SCN￣ および I￣ を配位子とする Cu(II) 錯体の非水溶媒ポーラログラフィー－ | |||||||
| 言語 | ||||||||
| 言語 | jpn | |||||||
| 資源タイプ | ||||||||
| 資源タイプ | departmental bulletin paper | |||||||
| 著者 |
村上, 光博
× 村上, 光博
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| 著者(ヨミ) | ||||||||
| 姓名 | ムラカミ, ミツヒロ | |||||||
| 著者別名 | ||||||||
| 姓名 | MURAKAMI, Mitsuhiro | |||||||
| 抄録 | ||||||||
| 内容記述タイプ | Abstract | |||||||
| 内容記述 | Electrochemical reductions of copper (II) complexes with SCN￣, Py and I￣ were studied in dimetylformamide (DMF) containing tetraethylammonium perchlorate. These copper (II) complexes were precipitated in aqueous solutions as a double salt by addition of nitron to a mixture of copper (II) and SCN￣ ions or that of copper (II) and Py. These products were dissolved in DMF. The DMF solutions were studied by polarography and cyclic voltammetry. At the dropping mercury electrode, the polarographic wave corresponding to the reduction of Cu (I) to Cu (O) appeared at rather negative potential, however, the reductiog wave of Cu (II) to Cu (I) was obscured because of oxidation waves of ligands. At the platinum electrode, the quasi-reversible reduction wave of Cu (II) to Cu (I) was observed at a less negative potential in cyclic voltammetry. These facts showed that the Cu (II) complexes are reduced to Cu (I), and thereafter to Cu (0). | |||||||
| 書誌情報 |
奈良教育大学紀要. 自然科学 巻 26, 号 2, p. 7-13, 発行日 1977-11-15 |
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| ISSN | ||||||||
| 収録物識別子タイプ | ISSN | |||||||
| 収録物識別子 | 05472407 | |||||||
| 書誌レコードID | ||||||||
| 収録物識別子タイプ | NCID | |||||||
| 収録物識別子 | AN00181070 | |||||||
| 著者版フラグ | ||||||||
| 出版タイプ | VoR | |||||||
| その他のタイトル | ||||||||
| その他のタイトル | The Electrode Reactions of Copper (II) Complexes in Nonaqueous Solvents Polarography of Copper(II) Complexes with SCN￣, Py and I￣. | |||||||
| 出版者 | ||||||||
| 出版者 | 奈良教育大学 | |||||||
