WEKO3
アイテム
ニトロフェノールのジメチルホルムアミド中におけるポーラログラフ的還元
http://hdl.handle.net/10105/3096
http://hdl.handle.net/10105/30963834e175-8353-4df4-89da-3c42daff1b1c
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
NUE18_2_13-20.pdf (503.9 kB)
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| アイテムタイプ | 紀要論文 / Departmental Bulletin Paper(1) | |||||||||
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| 公開日 | 2010-04-22 | |||||||||
| タイトル | ||||||||||
| タイトル | ニトロフェノールのジメチルホルムアミド中におけるポーラログラフ的還元 | |||||||||
| 言語 | ||||||||||
| 言語 | jpn | |||||||||
| 資源タイプ | ||||||||||
| 資源タイプ | departmental bulletin paper | |||||||||
| 著者 |
新居, 敏男
× 新居, 敏男
× 川瀬, 幸雄
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| 著者(ヨミ) | ||||||||||
| 姓名 | アライ, トシオ | |||||||||
| 著者(ヨミ) | ||||||||||
| 姓名 | カワセ, ユキオ | |||||||||
| 著者別名 | ||||||||||
| 姓名 | ARAI, Toshio | |||||||||
| 著者別名 | ||||||||||
| 姓名 | KAWASE, Yukio | |||||||||
| 抄録 | ||||||||||
| 内容記述タイプ | Abstract | |||||||||
| 内容記述 | The AC and DC polarographic studies of nitrophenols and p-nitrophenol sodium have been carried out in dimethylformamide. o-Nitrophenol gives two waves; the first wave has a wave height of one electron reduction and corresponds to the formation of nitrophenol anion radical, which has a intramolecular hydrogen bond, and the second wave has a wave height of five electrons reduction and corresponds to the formation of o-aminophenol. m-Nitrophenol gives four waves; both, the first and second wave have a wave height of one electron reduction and the reactions are reversible. The third shows a small wave height and the fourth appeared at about - 2.15 V. In the presence of phenol this substance gives two new waves, corresponding to two electrons reduction respectively. p-Nitrophenol gives two waves; the first wave corresponds to a reduction of phenolic hydrogen and the second wave is ascribed to the formation of dianion radical. In the presence of phenol the second wave grows to nearly four times the previous height and the third wave appears. These results are discussed in connection with the report of the ESR study of nitrophenol anion radical obtained by the electrolytic reduction. | |||||||||
| 書誌情報 |
奈良教育大学紀要. 自然科学 巻 18, 号 2, p. 13-20, 発行日 1969-11-29 |
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| ISSN | ||||||||||
| 収録物識別子タイプ | ISSN | |||||||||
| 収録物識別子 | 05472407 | |||||||||
| 書誌レコードID | ||||||||||
| 収録物識別子タイプ | NCID | |||||||||
| 収録物識別子 | AN00181070 | |||||||||
| 著者版フラグ | ||||||||||
| 出版タイプ | VoR | |||||||||
| その他のタイトル | ||||||||||
| その他のタイトル | Polarographic Reduction of Nitrophenols in Dimethylformamide | |||||||||
| 出版者 | ||||||||||
| 出版者 | 奈良教育大学 | |||||||||
